The Sorceress from Dragon's Crown. Paint Tool Sai for linework and the color. I've never used Sai before, and it took some getting used to. The stabilizer is amazing, and the ink looks a million times better than Photoshop. I'll probably re-visit some of my older work with it.
Be sure to check out the wallpaper versions as well:
16x9 Desktop WallpaperMobile (iPhone) Wallpaper16x9 Mobile (iPhone 5) Wallpaper